← All spectra

Iron Oxide Siderite

Core loss FeCO3 · Alex Gloter · added 2008-02-08 · Beam energy and angles known · History

Sign in to save

Loading spectrum…

Drag to zoom, double-click to reset.

The maximum L3 line of the iron divalent FeCO3 siderite has been measured 1.6 eV lower in energy with respect to the L3 line maximum of hematite. Both samples deposited onto the same grid. We use the hematite as a Fe3+ reference, maximum of the L3 line set at 710.5 eV to match with some XAS previously reported work. see Kuiper et al., Phys. Rev. Lett. 70, 1549 - 1552 (1993) Energy resolution improved by Richardson-Lucy deconvolution Analyst: A. Gloter, A. Chen. Temperature: Room.

Use in HyperSpy
import exspy

spectra = exspy.data.eelsdb(title="Iron Oxide Siderite", formula="FeCO3")
s = next(sp for sp in spectra if sp.original_metadata.json.id == 21710)
s.plot(plot_edges=True)

Specimen

Formula
FeCO3
Elements
Fe, C, O
Edges
Fe L2,3
Source and purity
Natural sample, strongly substituted (Fe0.79Mn0.12Mg0.07Ca0.02CO3)
Energy range
690.75 – 732 eV
Step
0.05 eV

Keywords

  • imported from old site

Treatment

Dark current corrected
No
Gain variation corrected
No

Acquisition

Microscope
STEM-VG
Gun
Cold FEG
Beam energy
100 kV
Convergence semi-angle
7.5 mrad
Collection semi-angle
24 mrad
Monochromated
No
Detector
Parallel: 666 Gatan

Other links

Please cite this spectrum

If you use this spectrum, cite the contributor and the EELS Data Base.

Alex Gloter. Iron Oxide Siderite (FeCO3). EELS Data Base, spectrum 21710, 2008. https://eelsdb.eu/spectra/iron-oxide-siderite/

Philip Ewels, Thierry Sikora, Virginie Serin, Chris P. Ewels and Luc Lajaunie. “A Complete Overhaul of the Electron Energy-Loss Spectroscopy and X-Ray Absorption Spectroscopy Database: eelsdb.eu.” Microscopy and Microanalysis 22, 717–724 (2016). doi:10.1017/S1431927616000179
BibTeX
@misc{Gloter2008eelsdb21710,
  author = {Alex Gloter},
  title = {Iron Oxide Siderite},
  howpublished = {EELS Data Base, spectrum 21710},
  year = {2008},
  url = {https://eelsdb.eu/spectra/iron-oxide-siderite/}
}

@article{ewels2016eelsdb,
  author = {Ewels, Philip and Sikora, Thierry and Serin, Virginie and Ewels, Chris P. and Lajaunie, Luc},
  title = {A Complete Overhaul of the Electron Energy-Loss Spectroscopy and X-Ray Absorption Spectroscopy Database: eelsdb.eu},
  journal = {Microscopy and Microanalysis},
  volume = {22},
  pages = {717--724},
  year = {2016},
  doi = {10.1017/S1431927616000179}
}
Download DspecTZA2vG.msa